Hmmmm, this is really odd Jamrock, I really don't know what to say, it seems like the database must be corrupting for you on start up somehow, giving the players different ID numbers. I've checked the unique I.D's in the editor on the .xml file and they are different to your screenshots. Currently no-one with that I.D. exists for the Kenny Dalglish in your screenshot, so why he has that ID in your game I have no idea. Also, I'm worried you have not set the facepack up correctly, as the Pele ID number on your screenshot should be showing you a picture of Sinisa Mihajlovic.
Also, it's strange that Souness and Rush aren't in your game, as they are in the Liverpool squad. It really seems like the database is not loading correctly. Are you merging it with any other editor files? As for Hunt and Heighway, they aren't done yet, and Liddell won't be in (too old, see concept).
Is anyone else having an issue with the facepack or players missing?